Reactivity of a Cl-boratabenzene Pt(II) complex with Lewis bases: generation of the kinetically favoured Cl-boratabenzene anion.
نویسندگان
چکیده
Complex [(IMes)(2)Pt(H)(ClBC(5)H(4)SiMe(3))] (IMes = 1,3-di(2,4,6-trimethylphenyl)imidazolin-2-ylidene) reacts with Lewis bases (L = pyridine, trimethylphosphine, acetonitrile, tert-butylisocyanide) to generate the kinetically favoured ion pairs [(IMes)(2)Pt(H)(L)][ClBC(5)H(4)SiMe(3)]. Over time, the formation of the thermodynamically favoured borabenzene-L adducts is observed with L = pyridine and trimethylphosphine.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 40 46 شماره
صفحات -
تاریخ انتشار 2011